Reconfiguration

What is reconfiguration

Who would win, League of Villains (My Hero Academia) or The Avengers (MCU)?

Round 1: League of Villains minus All for One and Nomus vs. MCU Avengers (pre-Civil War, post-AOU)-

Round 2: League Plus All for One, the Nomus and Overhaul vs. MCU Avengers (Post-Spiderman No Way Home, Excluding Captain America, Iron Man, Black Widow, Hulk)

Round 3: Full League of Villains (Manga version) vs. Comic Avengers (Only Captain America, Iron Man, Thor, Black Widow, Hawkeye, Hulk, Spiderman, Vision, Captain Marvel, Ant-Man, Scarlet Witch, Quicksilver and Doctor Strange)

Does user disintegrate self, moves personal moleculars into destination and recreates itself? Because that sounds more like Reconfiguration, honestly. Does Molecularportation work this way?