As part of his Dark Slayer fighting style, Vergil (Devil May Cry series) is immensely skilled in the art of Iaijutsu, able to draw his Yamato and kill demons in the blink of eye before placing his sword back in its sheath.
Goemon Ishikawa XIII (Lupin III)
Jonah Hex (DC Comics) has defeated Batman in a quickdraw.
Lucky Luke's (Lucky Luke) signature move is outdrawing his own shadow!
Princess Mira (Samurai Jack) is shown practicing her quick draw. She repeatedly slashes the drops of water falling from an icicle, to the other bounty hunters' amazement.